Inkcazo yeNkqubo yokuPlating yeNickel-Phosphorus engena-Electroless

1. Injongo

Ukumisela inkqubo yokugquma i-nickel engena-electroless, ulawulo lweeparameter, kunye neemfuno zomgangatho, ukuqinisekisa umgangatho ozinzileyo wokugquma ohlangabezana nemigangatho yabathengi neyehlabathi.

2. Ububanzi

Isebenza kwi-electroless nickel plating kwi-carbon steel, i-stainless steel, kunye ne-copper alloys. Ayisebenzi kwi-magnesium alloys, i-titanium alloys, okanye ezinye iinkqubo ezikhethekileyo.

3. Iingxelo eziQhelekileyo

  • • GB/T 13913-2008 – Iingubo ze-alloy ze-nickel-phosphorus ezizenzekelayo
  • • GB/T 6461-2002 – Uvavanyo lweesampuli zovavanyo kunye nezinto ezenziwe ngentsimbi kunye nezinye izinto ezingaphiliyo kwiziseko zentsimbi emva kovavanyo lokugqwala
  • • I-ASTM B733-18 – Inkcazelo Esemgangathweni Yeengubo ZeNickel-Phosphorus Ezizenzekelayo (Ezingena-Electro)
  • • ISO 4527:2003 – Iingubo zesinyithi – Iingubo ze-nickel-phosphorus alloy ezizenzekelayo (ezingenambane)
  • • GB/T 5270-2005 – Iingubo zesinyithi kwi-substrates zesinyithi – Iingubo ezifakwe nge-electroplated kunye neekhemikhali – Iindlela zovavanyo lokuncamathelisa

4. Umgaqo weNkqubo

I-electroless nickel plating yinkqubo yokubeka iikhemikhali ezizenzekelayo apho i-sodium hypophosphite inciphisa ii-ion ze-Ni²⁺ ukuze zenze i-Ni-P alloy coating.

Indlela yokusabela:

  • • I-Anodic oxidation: H₂PO₂⁻ + H₂O → H₂PO₃⁻ + 2H⁺ + 2e⁻
  • • Unciphiso lweCathodic: Ni²⁺ + 2e⁻ → Ni
  • • Ukufakwa kwe-phosphorus kunye: H₂PO₂⁻ + 2H⁺ + e⁻ → P + 2H₂O

Ukwahlulwahlulwa kwengubo ngokomxholo we-phosphorus:

Uhlobo Ubungakanani bephosphorus
I-Low-P 1–5%
I-Mid-P 5–10%
I-High-P 10–15%

5. Ukuhamba kweNkqubo

Ukuhlolwa → Ukususa amafutha → Ukuhlamba okushushu → Ukuhlamba okugelezayo → Ukuqhotsa → Ukuhlamba → Ukuvuselela → Ukuhlamba kwe-DI → Ukucoca okungenambane → Ukubuyisela → Ukuhlamba okuphambeneyo kwamanqanaba amathathu → Ukuhambisa → Ukuhlamba kwe-DI → Ukomisa → Ukuhlola → Ukupakisha

I-Nickel engena-Electro1
I-Nickel engena-Electro1

6. Iiparameter zeNkqubo eziPhambili

Ipharamitha Uluhlu lolawulo Amagqabaza
Uxinzelelo lweNi²⁺ 8–12 g/L Icetyiswayo yi-9–10 g/L
I-sodium hypophosphate 25–35 g/L Umlinganiselo we-Molar kwi-Ni²⁺: 2.5–3.5:1
Iarhente edibanisayo (i-sodium citrate) 30–40 g/L Iqinisa ii-ion ze-nickel
I-Buffer (i-sodium acetate) 15–25 g/L Igcina uzinzo lwe-pH
ixabiso le-pH 4.5–5.5 (Phakathi/phezulu-P) Ilungiswe nge-ammonia okanye i-sodium carbonate
Ubushushu 85–90℃ Eyona ilungileyo 88±1℃
Iyalayisha 0.5–1.5 dm²/L Ukulayisha okuphezulu kunciphisa izinga lokufakwa
Izinga lokufaka imali 15–25 μm/h Iyancipha xa uhlamba luguga
Ixesha imizuzu eli-15–60 Kuxhomekeke kubukhulu obufunekayo
Ukuphazamiseka Umoya woomatshini okanye ophantsi koxinzelelo Kucetyiswa ukuhamba okanye ukujikeleza kwezixhobo zomsebenzi
Ukuhluza Ukuhluza okuqhubekayo, umlinganiselo we-5–10 μm Isusa amasuntswana, ithintela ukuqhekeka

7. Iinkcukacha zeMveliso kunye nokukwazi ukugquma

7.1 Uluhlu lobungakanani bezinto zokusebenza

Into Ipharamitha
Ubungakanani obukhulu 1500×800×600 mm
Ubungakanani obuncinci 5×5×5 mm
Ubunzima obukhulu 200 kg
Ubunzima obuncinci 1 g

7.2 Ubungakanani bokutyeba kweCoating

Uhlobo Uluhlu lokutyeba Isicelo esiqhelekileyo
Iindawo ezichanekileyo 5–10 μm Imisonto, ii-valve cores, izinto ze-hydraulic
Iindawo ezisemgangathweni 10–50 μm Iindawo ezixhathisa ukugqwala kunye nokuguguleka ngokubanzi
Ukwaleka okutyebileyo 50–100 μm Ukulungiswa kokunxiba, iindawo ezinobungozi kakhulu

Ukufana: ±10% (iinxalenye eziqhelekileyo); ±15% (iimo ezintsonkothileyo)

7.3 Iipropati zokugquma

Ipropati Njengoko ipleyitiwe Iphathwe ngobushushu (400℃ × 1h) Amagqabaza
Ubunzima (HV) ≥500 HV ≥800 HV Unyango lobushushu lonyusa ubulukhuni
Ukunamathela ≤ Ibanga loku-1 (GB/T 5270) Akukho kuxobuka, akukho kuqhekeka
Uvavanyo lokutshiza ngetyuwa (i-NSS, i-5% ye-NaCl, i-35℃) ≥24 iiyure (Phakathi-Phakathi)
≥72 iiyure (High-P)
Ngokweemfuno zomthengi ngamnye
Ukugquma ≤1 inqaku/cm² Ngokwesiqhelo ayingeni mingxunya ≥25 μm
Ukuxhathisa 50–100 μΩ·cm 30–60 μΩ·cm

Unyango lobushushu: 400℃ ±10℃, iyure e-1, umoya/isithando somlilo sipholile.

8. Amandla eMveliso

Into Umthamo
Umthamo wetanki enye 2–5 m³
Ubunzima beqela 500–1500 kg
Umthamo wemihla ngemihla Iitoni ezi-3–8
Umthamo wenyanga Iitoni ezingama-80–200

Qaphela: Ubungakanani bokwenyani buxhomekeke kwijiyometri, ubukhulu, kunye nokuguga kwebhafu.

9. Uhlolo loMgangatho

9.1 Izinto zokuhlola

Into Indlela Izihlandlo Ikhrayitheriya yokwamkelwa
Ubukhulu I-XRF / imakroskopu ye-metallographic Amanqaku angama-≥3 ngomdlalo ngamnye ngebhetshi nganye Umzobo weDibana; uphuhliso oluphezulu ≤10%
Ukuqina Ubulukhuni be-HV0.1 micro Kanye ngeshifti nganye ≥500 HV (njengoko ibekwe epleyitini); ≥800 HV (HT)
Ukunamathela Ifayile/ukugoba/ukunqunyulwa okunqamlezileyo+iteyiphu Isiqwenga esinye ngebhetshi nganye Ibanga ≤1, akukho kuxobuka
Inkangeleko Okubonakalayo (ukukhanya okuqhelekileyo) 100% Iyunifomu eqaqambileyo; akukho ziphene
Ityuwa etshizwayo I-NSS 5% NaCl, 35℃ Ngebhetshi/utshintsho ngalunye I-Mid-P ≥24 h; I-High-P ≥72 h
Ubungakanani bephosphorus I-EDS / iikhemikhali Indlu yokuhlambela entsha yeveki nganye / 1–5% / 5–10% / 10–15%

9.2 Ulwahlulo lweNkangeleko

Ibanga Inkcazo
Ibanga A Ifanayo eqaqambileyo/engakhanyi kangako, ayinaziphene
Ibanga B Amanzi amancinci/iindawo zokukhonkxa, akukho mingxunya/ukuxobuka
Ibanga C Ukwahluka kombala okuncinci/okuncinci, ukusebenza kulungile
Yala Ukuphosa, ukuxobula, ukutsiba ipleyiti, ukutsha, umahluko omkhulu wombala

10. Ukusombulula iingxaki

Ingxaki Unobangela onokwenzeka Isisombululo
Ukunamathela okubi Ukususa/ukugalela amafutha okungaphelelanga; ukungasebenzi kakuhle Phucula unyango lwangaphambi konyango; yandisa ukusebenza
Ukungqubana/uburhabaxa Amasuntswana abhafini; i-pH ephezulu ibangela ukuhla kwe-pH Ukuphucula ukuhluza (5 μm); i-pH ephantsi
Ukwaleka okungwevu/okumnyama I-Ni²⁺/hypophosphate ephantsi; i-pH/ubushushu obuphantsi Yongeza iikhemikhali; pH 4.8–5.2; shushu ukuya kuma-88℃
Tsiba ipleyiti Ukungasebenzi kwendawo; ioyile eseleyo/i-oxide Phucula ukusebenza; phinda unciphise amafutha
Izinga lokufaka eliphantsi Ubushushu obuphantsi/iNi²⁺/inciphisa; i-pH engekho; ibhafu egugileyo Fudumeza ukuya kuthi ga kwi-88–90℃; lungisa i-pH; hlaziya ibhafu
Ukubola kwebhafu Ubushushu obugqithisileyo; i-pH ephezulu; ukongezwa ngokukhawuleza; umthwalo ophantsi Yeka ukufudumeza; i-pH ephantsi; nciphisa ukuhlamba

11. Ukhuseleko

  • • I-PPE: Iiglavu ze-asidi/ze-alkali, iiglasi zokukhusela amehlo, i-apron, umphefumli (i-ammonia/ii-asidi).
  • • Ukugcinwa kweekhemikhali: Hlukanisa i-nickel sulfate, i-hypophosphite, ii-asidi, ii-alkali; kude nobushushu/izinciphisi.
  • • Izithintelo: Musa ukuxuba i-conc. acid + hypophosphite (i-phosphine enetyhefu). Nyibilikisa izinto eziqinileyo emanzini e-DI kuqala.
  • • Umoya ophumayo: Umsi womoya ophumayo ongaphezulu kweetanki (ukususwa kwehydrogen).
  • • Ingxamiseko: Ukuhlamba amehlo, ishawa, umgubo owomileyo/isitshizi sokucima umlilo se-CO₂, isixhobo sokuphefumla, isixhobo sokuchitha.

12. Ukhuseleko lweNdalo

  • • Amanzi amdaka: Amanzi amdaka ahlukeneyo; i-pH ye-precipitate 9–10 + PAC/PAM; i-Ni <0.5 mg/L.
  • • Inkunkuma enobungozi: Ukuhlamba okuchithiweyo, izihluzi, i-activator, i-Ni sludge – ukulahla okunelayisenisi kunye ne-manifest.
  • • Ukukhupha umoya: Umoya ophuma rhoqo; jonga i-ammonia/hydrogen kwi-GB 16297 nganye.
  • • Amandla/amanzi: Zigqume ii-insulation kwiitanki; hlambulula ngamanzi ajikelezayo; ukugcwalisa okuxineneyo.

13. Ulwakhiwo lweBath (iPhosphorus ephakathi, iinxalenye eziqhelekileyo)

Ikhemikhali Ukugxila Umsebenzi
I-NiSO₄·6H₂O 25–35 g/L Ityuwa ephambili, umthombo weNi²⁺
NaH₂PO₂·H₂O 25–35 g/L Iarhente yokunciphisa, umthombo we-P
Na₃C₆H₅O₇·2H₂O 30–40 g/L Iarhente yokudibanisa
CH₃COONa·3H₂O 15–25 g/L i-pH buffer
I-lactic/propionic acid 5–10 mL/L Isikhawulezisi
Isizinzisi (thiourea) 1–2 mg/L Ithintela ukubola

Iinto zokuzilungisa:

1. Nyibilikisa i-NiSO₄, i-citrate, i-acetate kwi-1/3 yamanzi e-DI, i-60℃.

2. Nyibilikisa i-hypophosphite + i-lactic acid kwenye i-1/3.

3. Hlanganisa, zalisa ukuya kutsho kwivolumu, i-pH 4.8–5.2.

4. Yongeza isizinzisi, ubushushu bufikelele kwi-88℃, isihluzi, ipleyiti yovavanyo.

14. Amandla ezixhobo kunye nokuhlolwa

14.1 Izixhobo Eziphambili

Izixhobo Inkcazo
Itanki yokutyibiliza I-PP/PVC efakwe imiphetho, eshushu, nolawulo lobushushu
Ukuhluza Ipompo enganyangekiyo yi-asidi + indlu, 5–10 μm, 1–3×/h
Ulawulo lobushushu I-PID, ±1℃
I-oven yokomisa Umoya oshushu, 60–120℃
Isicoci se-ultrasonic 40 kHz, amandla ahlengahlengiswayo
Amanzi e-DI ≥10 MΩ·cm

14.2 Izixhobo zokuhlola

Izixhobo Ukuchaneka/Umgangatho
Ubukhulu be-XRF 0–200 μm, ±0.1 μm
Ubulukhuni obuncinci 10–1000 gf, GB/T 4340.1
Igumbi lokutshiza ityuwa GB/T 10125, ≥200 L
imakroskopu yeMetallographic 100–1000×, imayikromitha
imitha ye-pH ± 0.02, imbuyekezo yobushushu
Ibhalansi yohlalutyo 0.01 g

15. Uxwebhu kunye nokulandelelwa

  • Ingxelo yemveliso:Inombolo yenxalenye, ubungakanani, ubushushu, i-pH, ixesha, ubukhulu, umqhubi.
  • Ilog yokuhlamba:I-Ni²⁺ yemihla ngemihla, i-hypophosphite, i-pH; izongezo; ukucoca/ukuhluza.
  • Ingxelo yokuhlolwa:Ubukhulu, ubulukhuni, ukunamathela, inkangeleko, ityuwa yokutshiza.
  • Ulondolozo:Ukulinganisa, ukugcinwa kwepompo, ukukhupha ii-scaling, ukujonga iifeni (ngekota).

Ukugcinwa:≥Iminyaka emi-3 (≥Iminyaka eli-10 yemoto/yezonyango). Ingalandelelwa kwi-batch/bath cycle.

16. Izibonelelo ezongezelelweyo

  • • Ihlolwa minyaka le liSebe lezobuGcisa.
  • • Iimfuno ezikhethekileyo zabathengi (ityuwa yokutshiza, ubulukhuni, ukusasazwa, ukubhityaniswa kwe-H) zibhalwe phantsi kwaye zilandelwa.
  • • Iimveliso ezintsha: Uvavanyo oluncinci kuqala; imveliso ngobuninzi emva kokuphumelela zonke iimvavanyo.
  • • Ukulawula imveliso kunye nokuhlolwa kwabathengi.

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Ixesha leposi: Meyi-18-2026